Step 1) Solve the first equation for #x#:
#2x + 3y = 16#
#2x + 3y - color(red)(3y) = 16 - color(red)(3y)#
#2x + 0 = 16 - 3y#
#2x = 16 - 3y#
#(2x)/color(red)(2) = (16 - 3y)//color(red)(2)#
#x = 8 - 3/2y#
Step 2) Substitute #8 - 3/2y# for #x# in the second equation and solve for #y#:
5(8 - 3/2y) - 2y = 21#
#40 - 15/2y - 2y = 21#
#40 - 15/2y - (2/2 xx 2)y = 21#
#40 - 15/2y - 4/2y = 21#
#40 - 19/2y = 21#
#40 - color(red)(40) - 19/2y = 21 - color(red)(40)#
#0 - 19/2y = -19#
#-19/2y = -19#
#-2/19 xx -19/2y = -2/19 xx -19#
#38/38y = 2#
#y = 2#
Step 3) Substitute #2# for #y# in the solution for the first equation at the end of Step 1 and calculate #x#:
#x = 8 - (3/2 xx 2)#
#x = 8 - 3#
#x = 5#
The solution is #x = 5# and #y = 2#