Question #8e7c0

1 Answer
Nov 8, 2017

The central atom is #"S"#. Its hybridization is #"sp"^3#.

Explanation:

Central atom

The central atom is the least electronegative atom.

The electronegativities are

  • #"S"color(white)(ll)"= 2.58"#
  • #"O ="color(white)(l)"3.44"#
  • #"Cl = 3.16"#

S has the lowest electronegativity, so it becomes the central atom.

We draw a skeleton structure with the #"S"# atom in the middle.

Skeleton
(Adapted from ChemSpider)

Then we add the electrons.

#"1S + 2O + 2Cl = (6 + 12 + 14) electrons = 32 electrons"#

After minimizing formal charges, we get the structure

SO2Cl2
(Adapted from ChemSpider)

Hybridization of #"S"#

There are four electron domains around the sulfur atom.

According to VSEPR theory, this corresponds to a tetrahedral structure.

SO2Cl2
(From Wikipedia)

The hybridization that gives a tetrahedral structure is #"sp"^3#.