Question #b15c6

1 Answer
Dec 28, 2017

This requires the Nernst equation,

#E = E^° - (0.0592)/n * logQ#

We have an equilibrium here,

#2Cr(s) + 3Cl_2(g) to 6Cl^(-)(aq) + 2Cr^(3+)(aq)#,

where #E° = 0.618V#, and

#K = ([Cl^-]^6[Cr^(3+)]^2)/([Cl_2]^3)#

Hence,

#1.77V = 0.618V - (0.0592)/6 * log((1^6*x^2)/(1^3))#
#therefore x = [Cr^(3+)] approx 4.43*10^-26M#

This is fairly unreasonable, I agree with the Ernest and Michael.