Question #e4bba

1 Answer
Jul 21, 2015

A species contains an equal number of sigma and pi bonds if it contains the same number of single and triple bonds.

Explanation:

perso.numericable.fr

A double bond always contains one σ bond and one π bond.

So the number of double bonds doesn't matter.

They always contribute an equal number of σ and π bonds, no matter how many double bonds there are.

A single bond has one σ bond, while a triple bond has one σ and two π bonds.

So each single bond-triple bond pair has two σ bonds and two π bonds.

Few molecules have exactly the same number of σ and π bonds.

Some that I can think of are:

carbon dioxide: #"O=C=O"#

carbon suboxide: #"O=C=C=C=O"#

sulfur cyanide: #"N≡C-S-C≡N"#

tetracyanoethylene:

Tetracyano