Given
#m_w->"Mass of water"="its volume"xx"density#
#=25cm^3xx1g/(cm^3)=25g#
#t_w->"Initial temperature of water"=23^@C#
#m_(Cd)->"Mass Cadmium"=65.5g#
#t_(Cd)->"Initial temperature of Cd"=100^@C#
#C_w->"Sp.heat capacity of water"=4.184J/(g^@C)#
#C_(Cd)->"Sp.heat capacity of Cd"=0.2311J/(g^@C)#
Let the final temperature of the system be #t^@C#
So by calorimetric principle
#"Heat lost by Cd" = "Heat gained by water"#
#=>m_(Cd)xxC_(Cd)xx(t_(Cd)-t)= m_wxxC_wxx(t-t_w)#
#=>65.5xx0.2311xx(100-t)= 25xx4.184xx(t-23)#
#=>(65.5xx0.2311)/(25xx4.184)xx(100-t)= (t-23)#
#=>0.1447xx(100-t)= (t-23)#
#=>14.47-0.1447t= (t-23)#
#=>1.1447t=37.47#
#=>t=37.47/1.1447~~32.73^@C#