A #"98.8% w/w"# solution of sulfuric acid has #rho=1.84*g*mL^-1#. What is the molar concentration of the acid?

1 Answer
Oct 22, 2017

I take it you want to make a #1*L# volume of a #3.0*mol*L^-1# solution.....

Explanation:

And, as I have said before, there is a very important practical issue to be considered when we dilute a strong acid. Because addition of a strong acid to water results in an EXOTHERM, i.e. an evolution of heat as the acid is hydrated, we ALWAYS ADD ACID to WATER, and NEVER the reverse....

i.e. #"when you spit in acid it spits back, so don't spit in the acid"#

And now finally to business...

We use the relationship...#"concentration"="moles of solute"/"volume of solution"#

And thus #"moles of solute"="volume of solution"xx"concentration"#

Here this gives ........#"moles of solute"=1*Lxx3.0*mol*L^-1=3.0*mol#

And so from the conc. acid...we need...#3.0*molxx98.08*g*mol^-1=294.2*g# WITH RESPECT TO SOLUTE....

And this is a volume of.....#(294.2*g)/(98%xx1.84*g*mL^-1)=163.2*mL#, which is then diluted to a #1*L# volume with water.

When you do the dilution you must be togged up in the safety gear: safety specs or optical specs, and a lab coat to protect your clothes. This is an absolute requirement.....

For your information quotient..... #1*cm^3=1xx(10^-2*m)^3=1xx10^-6*m^3=1/1000xx1/1000xx1*m^3=1/1000xx1*L=10^-3L=1*mL................# as required. The point I try to make is that #cm^3# and #mL# are the SAME unit of volume.