Given the illustration, what is the activation energy for the transition #BrarrA#?

2 Answers
Oct 23, 2017

Well, what is #(23-7)*kcal*mol^-1#?

Explanation:

We assess the transition #ArarrD#. The activated complex is at the top of the energy well, at #DeltaG^@=23*kcal*mol^-1#. Since we start with #A#, whose free energy is #7*kcal*mol^-1# is the difference between minimum and maximum energies.....#E_a=16*kcal*mol^-1#....

Oct 26, 2017

You answered the wrong question.

Explanation:

You gave the activation energy for the reaction going from A to B.

The question asked for the activation energy for the reaction going from B to A (the reverse direction).

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Going from B to A, you are starting at 12 kcal/mol and moving to the transition
state #bb‡# at 18 kcal/mol.

#E_text(a) = "(18 - 12) kcal/mol = 6 kcal/mol"#