A large family of boron-hydrogen compounds has the general formula BxHy . One member of this family contains 88.5% B ;the remainder is hydrogen. What is its empirical formula?

1 Answer
Mar 26, 2018

Well, we got the empirical formula #BH_2#

Explanation:

We are given that the stuff contains #85%# boron by mass... (well we assumed it was by mass, but this is the standard scenario).

And so we ASSUME a #100*g# mass of the borane.....and we interrogate the empirical formula....

#"Moles of boron"=(85*g)/(10.81*g*mol^-1)=7.86*mol.#

#"Moles of hydrogen"=(15*g)/(1.00794*g*mol^-1)=14.882*mol.#

We divide thru by the SMALLER molar quantity, that of boron, to get the empirical formula, which is the simplest whole number ratio representing constituent atoms in a species...

And so we got #B_((7.86*mol)/(7.86*mol))H_((14.882*mol)/(7.86*mol))-=BH_2#...and there are several known borane hydrides with this empirical formula....