Are the two gases he made the same?

A chemist reacts 50.0 g sulfur with 50.0 g oxygen to make 83.4 grams of a gas, along with some leftover sulfur. In a different experiment, he reacts 20.0 grams of sulfur with 30.0 grams of oxygen to make 49.9 grams of a gas, along with some leftover oxygen.

1 Answer
Dec 13, 2017

Yes....both scenarios yield #SO_3#, #"sulfur trioxide...."#

Explanation:

Initially #83.4*g# of gas was made from #33.4*g# sulfur, and #50.0*g# oxygen....

And thus #"moles of sulfur"=(33.4*g)/(32.06*g*mol^-1)=1.04*mol#

And #"moles of oxygen"=(50.0*g)/(16.00*g*mol^-1)=3.125*mol#

We divide thru by the SMALLER molar quantity to get an empirical formula of #S_((1.04*mol)/(1.04*mol))O_((3.125*mol)/(1.04*mol))=SO_3#

And in the second scenario, we use #20.0*g# sulfur and #29.9*g# oxygen to make #49.9*g# of compound....

And thus #"moles of sulfur"=(20.0*g)/(32.06*g*mol^-1)=0.624*mol#

And #"moles of oxygen"=(29.9*g)/(16.00*g*mol^-1)=1.87*mol#

We go thru the same rigmarole....to get an empirical formula of #S_((0.624*mol)/(0.624*mol))O_((1.87*mol)/(0.624*mol))=SO_3#.

What was the other possible sulfur oxide?