We will need the moles ethanol for both calculations.
#2.00color(red)cancel(color(black)("g C"_2"H"_5"OH"))xx(1"mol C"_2"H"_5"OH")/(46.069color(red)cancel(color(black)("g C"_2"H"_5"OH")))="0.043413 mol C"_2"H"_5"OH"#
I am leaving a couple of extra digits to reduce rounding errors. The final answers will be rounded to three significant figures.
MOLARITY
#"molarity"="moles solute"/"L of solution"#
We need to convert #"102 mL of solution"# to #"L"#.
#"1 L"##=##"1000 mL"#
#102color(red)cancel(color(black)("mL"))xx(1"L")/(1000color(red)cancel(color(black)("mL")))="0.102 L"#
#"molarity"=("0.043413 mol C"_2"H"_5"OH")/(0.102"L")="0.426 mol C"_2"H"_5"OH/L"="0.426 M"# (rounded to three significant figures)
MOLALITY
#"molality"="moles solute"/"kg solvent"#
Water is the solvent.
We need to convert #"100.0 g"# water to #"kg"#.
#"1 kg"##=##"1000 g"#
#100.0color(red)cancel(color(black)("g"))xx(1"kg")/(1000color(red)cancel(color(black)("g")))="0.1000 kg"#
#"molality"=(0.043413"mol C"_2"H"_5"OH")/(0.1000"kg H"_2"O")="0.434 mol/kg"="0.434 m"# (rounded to three significant figures)