Do all of the following molecules contain at least one bond angle at 120 degrees: SeS3, SeS2, PCl5, TeCl4, ICI3, and XeCl2?

1 Answer
Feb 9, 2016

No, because two of the molecules have no bond angles at 120 °.

Explanation:

To answer this question, you must draw the Lewis structures of the compounds and determine their VSEPR shapes.

#"SeS"_3#

The Lewis structure of #"SeS"_3# is

SeS3
(from www.homeworklib.com)

This is an #"AX"_3# molecule, and its geometry is trigonal planar.

All bond angles in a trigonal planar molecule are approximately 120 °.

#"SeS"_2#

The Lewis structure of #"SeS"_2# is

#:stackrel(". .")("S")=stackrel(". .")("Se")=stackrel(". .")("S"):#

This is an #"AX"_2"E"# molecule.

Its electron geometry is trigonal planar.

The bond angle in an #"AX"_2"E"# molecule is approximately 120 °.

#"PCl"_5#

The Lewis structure of #"PCl"_5# is

www.chem.purdue.edu

This is an #"AX"_5# molecule, and its geometry is trigonal pyramidal.

The equatorial bond angles in a trigonal bipyramidal molecule are all 120 °.

#"TeCl"_4#

The Lewis structure of #"TeCl"_4# is

bilbo.chm.uri.edu

This is an #"AX"_4"E"# molecule.

Its electron geometry is trigonal pyramidal.

The equatorial bond angle between the equatorial #"Te-Cl"# bonds is approximately 120 °.

#"ICl"_3#

The Lewis structure of #"ICl"_3# is

www.chemistry.mcmaster.ca

This is an #"AX"_3"E"_2# molecule.

Its electron geometry is trigonal pyramidal, and its molecular geometry is T-shaped.

The #"I-Cl"# bond angles in a T-shaped molecule are both approximately 90 °.

#"XeCl"_2#

The Lewis structure of #"XeCl"_2# is

www.webassign.net

This is an #"AX"_2"E"_3# molecule.

Its electron geometry is trigonal pyramidal, with the lone pairs in the equatorial positions.

The molecule is linear, with a #"Cl-Xe-Cl"# bond angle of 180 °.