Does free energy affect the reaction rate?

1 Answer
Jan 3, 2016

No.

Explanation:

For every chemical reaction, there are two domains:

  • Domain of thermodynamics : Determines in which direction the reaction will happen spontaneously.
  • Domain of kinetics : Determines the reaction pathway. Shorter pathway will lead to a faster reaction.
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    #color(grey)("Image source: Zumdahl textbook")#

The free energy (#DeltaG#) is a thermodynamic factor, however, the reaction rate (#R#) is a kinetic factor, and therefore, they are independent of each other.