For the reaction #2"H"_2"S"+"SO"_2->3"S"+2"H"_2"O"#.what happens in this above reaction?

2 Answers
May 3, 2018

hydrogen sulfide plus sulfur dioxide react to form sulfur and water

Explanation:

Given: #2H_2S + SO_2 -> 3S + 2H_2O#

2 moles of hydrogen sulfide combines with 1 mole of sulfur dioxide react to form 3 moles of sulfur and 2 moles of water.

This sounds like a reaction that you would encounter at Yellowstone National Park.

May 3, 2018

This is a so-called #"comproportionation reaction"#, i.e. a redox process where oxidant and reductant give the SAME product...

Explanation:

Sulfide is oxidized to sulfur:

#S^(2-) rarr S(s) +2e^(-)# #(i)#

Sulfur dioxide is reduced to sulfur:

#SO_2(g) + 4H^+ +4e^(-) rarr S(s) +2H_2O(l)# #(ii)#

And we add #2xx(i)+(ii)# to retire the electrons to get...

#SO_2(g)+underbrace(2S^(2-) + 4H^+)_(-=2H_2S) +4e^(-)rarr 3S(s) +4e^(-) +2H_2O(l)#

To give after cancellation....

#SO_2(g)+2H_2S rarr 3S(s) +2H_2O(l)#

Is this balanced? If it is not, then it cannot be accepted as a representation of reality.