How are chemical bonds represented in the structural formula of a hydrocarbon?

1 Answer
Jan 26, 2017

By dashes, #-#; mind you, sometimes the dashes are understood.

Explanation:

Typically, hydrocarbons are represented by zig-zag lines, where each zig and each zag represents a methylene unit, i.e. #CH_2#, unless that carbon is otherwise substituted. The carbon termini are often explicitly drawn as methyls for clarity, i.e. #CH_3# (as per the 1st figure, but not the 2nd).

Given this scheme, #"n-pentane"#, #C_5H_12#, would be drawn as:

https://tse3.mm.bing.net/th?id=OIP.M01a22013385734273a629e440f02871bo0&pid=15.1&P=0&w=300&h=300

Sites of unsaturation along the chain, would be represented by double bonds, and of course #"2-pentene, "C_5H_10#, has the possibility of geometric isomerism:

https://tse1.mm.bing.net/th?id=OIP.Me5efb6081ea3d1bbab7b9955a6720b44o0&pid=15.1&P=0&w=239&h=168

Could I name this #"3-pentene"#? The olefin bond is at #C3# if I number the right most carbon as #C1#.

I do realize that this seems a lot to take in, and at first acquaintance it might appear insurmountable. Persist with it, and you will rapidly gain a working knowledge. In all examples you find the longest carbon chain before naming the beast.