How can you model half life decay?

1 Answer
Jul 3, 2016

The equation would be:

#[A] = 1/(2^(t"/"t_"1/2"))[A]_0#

Read on to know what it means.


Just focus on the main principle:

The upcoming concentration of reactant #A# after half-life time #t_"1/2"# becomes half of the current concentration.

So, if we define the current concentration as #[A]_n# and the upcoming concentration as #[A]_(n+1)#, then...

#[A]_(n+1) = 1/2[A]_n# #" "\mathbf((1))#

We call the (1) the recursive half-life decay equation for one half-life occurrence, i.e. when #t_"1/2"# has passed by only once. This isn't very useful though, because half-lives can range from very slow (thousands of years) to very fast (milliseconds!).

Let's go through another half-life, until we've gone through #\mathbf(n)# half-lives. For this, we rewrite #[A]_n# as #[A]_0# (the initial concentration), and #[A]_(n+1)# as #[A]# (the upcoming concentration).

Notice how #[A]_0# will always be the same, but #[A]# will keep changing over time.

#[A] = (1/2)(1/2)cdots(1/2)[A]_0#

#= (1/2)^n[A]_0#

#=> [A] = 1/(2^n)[A]_0# #" "\mathbf((2))#

Now we have (2), the equation for any number of half-life decays... once we know how many half-lives passed by.

However, (2) can be made more convenient since we know that each half-life takes #t_"1/2"# time to occur. When #n# half-lives occur, each one taking #t_"1/2"# to occur, it must occur over a set amount of time #t#. So:

#nt_"1/2" = t# #" "\mathbf((3))#

That means #n = t/t_"1/2"#, which is saying that we can divide the total time passed during the process by the time it takes to lose half of #A# again to get the number of half-lives that passed by.

Therefore:

#color(blue)([A] = 1/(2^(t"/"t_"1/2"))[A]_0)# #" "\mathbf((4))#

So, we can use (4) to determine half-lives of any typical radioactive element for which we know #t#, the time passed during the half-life decay(s) AND:

  • #[A]_0#, the initial concentration, and #[A]#, the upcoming concentration, OR
  • #([A])/[A]_0#, the fraction of the element left after time #t# passes.