I have a test for chemistry tom and my teacher is going to give me element and I have to tell if it's either polar or non-polar how do i tell? I know that I use the difference of electronegativity?

1 Answer
Feb 22, 2015

You can refer to polarity both in the context of bonds, whether or not a bond is polar, and in the context of molecules, whether or not you have a polar molecule.

I'll show you briefly a little bit about both.

For two atoms bonded together, the difference between the electronegativity values of the two atoms is sufficient to determine if the bond is polar or non-polar.


So, in order for a bond to be considered polar, the difference in electronegativity values must be greater than 0.5. For example, the bond between carbon is oxygen is polar because the EN value of carbon is 2.5 and that of oxygen is 3.5, which means a difference of 1.0.

On the other hand, the bond between carbon and hydrogen is considered non-polar because the difference in EN is 0.4.

On the other hand, for molecule to be polar you have to have both polar bonds (it's a must) and a favorable molecular geometry.


Think vector addition. Water is polar because it has two polar #"H-O"# bonds and two dipole moments that do not cancel each other out. #CO_2#, the molecule furthest to the right, has two polar #"C-O"# bonds but it is not a polar molecule because these dipole moments cancel each other out.

So, as a conclusion, you need EN difference for polarity of bonds, and EN difference plus molecular geometry for polarity of molecules.

By the way, diatomic molecules suchs as #O_2#, #F_2#, and #Cl_2# are non-polar because they have a non-polar bond; in their case, the difference in EN is zero.

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