In the following reaction, what is reactant being oxidized?

So confused, any help is very much appreciated!

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1 Answer
Jan 24, 2018

The metal....

Explanation:

Tin metal is oxidized up to stannic ion...#Sn^(4+)#..

#Sn(s) rarr Sn^(4+) + 4e^(-)# #(i)#

Meanwhile the nitrogen in nitrate #N(V+)# is REDUCED to #N(IV+)#...

#NO_3^(-) +2H^+ + e^(-) rarr NO_2(g) + H_2O# #(ii)#

For both half equations, charge and mass are balanced...so we simply add #(i)+4xx(ii):#

#Sn(s)+4NO_3^(-) +8H^+ + cancel(4e^(-)) rarr Sn^(4+) +4NO_2(g) + 4H_2O+cancel(4e^(-))#

to give,..

#Sn(s)+4NO_3^(-) +8H^+ rarr Sn^(4+) +4NO_2(g) + 4H_2O#

Charge and mass are balanced as required....

Alternatively, you could assign oxidation numbers, and proceed from there...