Question #ee86f

1 Answer

The #s# orbital can combine with any of the #p_x#, #p_y# or #p_z# orbitals.

Three #p# orbitals are all equivalent, so it doesn't matter which one the #s# orbital combines with.

Since the #p# orbitals are equivalent, the #x#, #y#, and #z# labels that we attach to them are completely arbitrary. We choose a label such as #p_z# purely for convenience.

For example, the diagram below uses the #p_y# and #p_z# orbitals to form the π bonds. So it uses the #p_x# orbitals to form the #sp# bonding orbitals.

Orbital structure of ethyne from www.citycollegiate.com.