The thimble contains #3.3 * 10^(-4)# moles of water.
To go from number of molecules to moles and vice versa, you can use Avogadro's number, which describes the number of atoms or molecules present in a mole of substance.
According to this, each mole contains exactly #6.022 * 10^(23)# atoms or molecules; in your case, 1 mole of water would contain #6.022 * 10^(23)# molecules of water.
Since #2.0 * 10^(20)# is a smaller number than #6.022 * 10^(23)#, you'll have less than 1 mole of water in a thimble.