For the #""_15^31P# isotope, #"Z, the atomic number"#, the subscript, is superfluous. The element is phosphorus, and #Z#, #"the atomic number"# #=# #15# BY DEFINITION.
The #"mass number"#, the superscript, is the number of massive particles, protons and neutrons, contained in the nucleus of the isotope, and this is given by the superscript. This is something you really should get your head round. Hydrogen has 3 common isotopes, #""^1H, "protium", ""^2H, "deuterium",# and #"tritium",""^3H. # Can you tell me the number of neutrons each nucleus contains?