Question #d772b

2 Answers
Mar 22, 2017

I tried this:

Explanation:

You have that an electron in jumping from one level to another (as in your case, going down) will release energy in form of a photon of light.
The energy correspondent to this jump can be evaluated using a formula from Bohr's Theory (you can find it in the part of Quantum Physics of your book near Bohr's Postulates or Hidrogen Spectrum or at http://hyperphysics.phy-astr.gsu.edu/hbase/hyde.html):
We start using:
#"Energy difference"=-13.6[1/n_1^2-1/n_2^2]# in #eV#

Where:
#n_1=2#
#n_2=4#
To get:
#"Energy"=-13.6[1/4-1/16]=-2.55eV# emitted during the transition.
For semplicity I now change it into Joules to get the usual units for frequency and wavelength:
I know that:
#1eV=1.6xx10^-19J#
so #2.55eV=4.1xx10^-19J#
I can get the frequency #f# knowing that for energy we have:
#E=hf# (where #h# is Planck's Constant)
so:
#f=E/h=(4.1xx10^-19)/(6.63xx10^-34)=6.2xx10^14Hz#
and for the wavelength #lambda#:
#lambda=c/f=(3xx10^8)/(6.2xx10^14)=4.851xx10^-7~~485nm#
By the way #c=3xx10^8m/s# is the speed of light in vacuum that will be the speed of your photon!

Chemistry 301

Mar 22, 2017

#sf((1))#

#sf(2.55color(white)(x)"eV")#

#sf((2))#

#sf(6.16xx10^(14)color(white)(x)"Hz")#

#sf((3))#

#sf(2.998xx10^(8)color(white)(x)"m/s")#

#sf((4))#

#sf(486.2color(white)(x)"nm")#

Explanation:

If you are working in electron volts then the energy of the electron in a particular energy level is given by:

#sf(E=(-13.6)/(n^2)" ""eV")#

hyperphysics.phy-astr.gsu.edu

Where n is the principal quantum number.

When n = 2:

#sf(E=(-13.6)/(2^2)=-3.40color(white)(x)"eV")#

When n = 4:

#sf(E=(-13.6)/(4^2)=-0.850color(white)(x)"eV")#

This means the transition energy will be the difference between the 2 values:

#sf(DeltaE=-0.850-(-3.40)=2.55color(white)(x)"eV")#

#sf((2))#

The electron volt is not the standard unit for energy so we must convert it to Joules. To do this we multiply by the electronic charge:

#sf(E=2.55xx1.602xx10^(19)" "J)#

#sf(E=4.085xx10^(-19)" "J)#

To find the frequency f we use the Planck Expression:

#sf(E=hf)#

Where h is the Planck Constant.

#:.##sf(f=E/h)#

#sf(f=(4.085xx10^(-19))/(6.626xx10^(-34))=6.165xx10^(14)" ""Hz")#

#sf((3))#

The photon will travel at the speed of light c . This is a universal constant:

#sf(c=2.998xx10^8color(white)(x)"m/s")#

#sf((4))#

The relationship we need is :

#sf(c=flambda)#

#:.##sf(lambda=c/f=(2.998xx10^(8))/(6.165xx10^(14))=0.4862xx10^(-6)" "m)#

#sf(lambda=486.2color(white)(x)nm)#