What do we mean by the term #"mole fraction"#, with respect to a solution?

1 Answer
Sep 30, 2017

Well the mole fraction, #chi#, of a component in solution.....

Explanation:

...is given by the quotient.....

#chi_"component"="moles of component"/"total moles of solute and solvent that comprise the solution"#

And as an example, we could dissolve #58.44*g# of sodium chloride in #1*L# of water to get near enuff to a #1*mol*L^-1# solution. (The volume would change negligibly upon dissolution.

And thus #chi_"sodium chloride"=((58.44*g)/(58.44*g*mol^-1))/((1000*g)/(18.01*g*mol^-1)+(58.44*g)/(58.44*g*mol^-1))#

#=0.0177#

But in a binary solution, #chi_"solute"+chi_"solvent"=1# by necessity.

And so #chi_"solvent"=1-chi_"NaCl"=0.982#...