When #"copper sulfate pentahydrate"# is heated, a colour change is observed. Why?

1 Answer
Dec 20, 2017

Well, this is an example of chemical change, so of course a colour change is expected.....

Explanation:

We gots....#underbrace(CuSO_4*5H_2O(s))_"lovely blue crystals" + Delta rarr underbrace(CuSO_4(s))_"white salt" + 5H_2O(l)#

In the hydrate, the copper is coordinated to water molecules....the water molecules leave the metal coordination sphere upon drying...

lookfordiagnosis.con

fphotoshelter.com

The watchglass on the right as we face it, contains anhydrous #CuSO_4(s)#...the colour change is beautiful, and dramatic.

The addition of water ligands modifies the electronic structure of the copper atom....