This is a long question, so I will show only the calculations for methane. You can use them as a pattern for the ethane and nitrogen calculations.
The results are in the table below.
ulbb(color(white)(l)"Item"color(white)(mm)"CH"_4color(white)(m)"C"_2"H"_6color(white)(m) "N"_2color(white)(ml)"Total")
"Vol. %"color(white)(mml)83.6color(white)(mll)12.5color(white)(mml)4color(white)(mml)100
ul("Mole %" color(white)(mlll)83.6color(white)(mll)12.5color(white)(mml)4color(white)(mml) 100)
"Moles" color(white)(mmll)83.6color(white)(mll)12.5color(white)(mml)4color(white)(mml) 100
ul("Mass/g"color(white)(m) 1341color(white)(mm)375.8color(white)(m)110color(white)(mm)1829)
"Mass %" color(white)(mlll)73.3color(white)(mll)20.6color(white)(mml)6color(white)(mml) 100
Mole percent
Since n∝V, the volume percent is the same as the mole percent,
Mass percent
Assume that we have 100 mol of gas. Then we have
"83.6 mol CH"_4, "12.5 mol C"_2"H"_6, and "4 mol N"_2
"Mass of CH"_4 = 83.6 color(red)(cancel(color(black)("mol CH"_4))) × ("16.04 g CH"_4)/(1color(red)(cancel(color(black)("mol CH"_4)))) = "1341 g CH"_4
Calculate the masses of ethane and nitrogen in the same way.
"Total mass = (1341 + 375.8 + 110) g = 1829 g"
"% CH"_4 = ("Mass of CH"_4)/("Total mass") × 100 % = (1341 color(red)(cancel(color(black)("g"))))/(1828 color(red)(cancel(color(black)("g")))) × 100 % = 73.3 %
Calculate the mass percent of ethane and nitrogen in the same way.