An electron changes from an n = 2n=2 to an n = 6n=6 energy state. What is the energy of the photon in joules?

1 Answer
Nov 27, 2017

4.85 * 10^(-19)4.851019 "J"J

Explanation:

The question wants you to determine the energy that the incoming photon must have in order to allow the electron that absorbs it to jump from n_i = 2ni=2 to n_f = 6nf=6.

A good starting point here will be to calculate the energy of the photon emitted when the electron falls from n_i = 6ni=6 to n_f = 2nf=2 by using the Rydberg equation.

1/(lamda) = R * (1/n_f^2 - 1/n_i^2)1λ=R(1n2f1n2i)

Here

  • lamdaλ si the wavelength of the emittted photon
  • RR is the Rydberg constant, equal to 1.097 * 10^(7)1.097107 "m"^(-1)m1

Plug in your values to find

1/lamda = 1.097 * 10^7color(white)(.)"m"^(-1) * (1/2^2 - 1/6^2)1λ=1.097107.m1(122162)

1/lamda = 2.4378 * 10^6 color(white)(.)"m"^(-1)1λ=2.4378106.m1

This means that you have

lamda = 4.10 * 10^(-7)color(white)(.)"m"λ=4.10107.m

So, you know that when an electron falls from n_i = 6ni=6 to n_f = 2nf=2, a photon of wavelength "410 nm"410 nm is emitted. This implies that in order for the electron to jump from n_i = 2ni=2 to n_f = 6nf=6, it must absorb a photon of the same wavelength.

![http://www.wondrousheaven.com/2017/07/11/](useruploads.socratic.org)

To find the energy of this photon, you can use the Planck - Einstein relation, which looks like this

E = h * c/lamdaE=hcλ

Here

  • EE is the energy of the photon
  • hh is Planck's constant, equal to 6.626 * 10^(-34)color(white)(.)"J s"6.6261034.J s
  • cc is the speed of light in a vacuum, usually given as 3 * 10^8 color(white)(.)"m s"^(-1)3108.m s1

As you can see, this equation shows you that the energy of the photon is inversely proportional to its wavelength, which, of course, implies that it is directly proportional to its frequency.

Plug in the wavelength of the photon in meters to find its energy

E = 6.626 * 10^(-34) color(white)(.)"J" color(red)(cancel(color(black)("s"))) * (3 * 10^8 color(red)(cancel(color(black)("m"))) color(red)(cancel(color(black)("s"^(-1)))))/(4.10 * 10^(-7) color(red)(cancel(color(black)("m"))))

color(darkgreen)(ul(color(black)(E = 4.85 * 10^(-19)color(white)(.)"J")))

I'll leave the answer rounded to three sig figs.

So, you can say that in a hydrogen atom, an electron located on n_i = 2 that absorbs a photon of energy 4.85 * 10^(-19) "J" can make the jump to n_f = 6.