Do kc have any unit?

1 Answer
Nov 22, 2017

Strictly...no......

Explanation:

#K_"eq"# is the so-called thermodynamic equilibrium constant....and thus for the reaction....

#A+Brightleftharpoons C+D#

#K_"eq"=([C][D])/([A][B])#....#K_"eq"# is properly dimensionless....

I grant that not all equilibria are set up like this, and conceivably we COULD have....

#A+BrightleftharpoonsC#

...the which, ostensibly, could have units. In these scenarios we use DIMENSIONLESS activities to report the concentration of #[A]#, #[B]#, and #[C]#.

And why do we make all these specifications? Well, because of the #"Gibbs Free Energy equation...."#, the which specifies that....

#lnK_"eq"=-(DeltaG^@)/(RT)#....and establishes the relationship of the thermodynamic equilibrium constant to the free energy, and of course we may only take #"logs"# of a dimensionless number....