Find #a, b# so that the system has unique solution: ? #x+y+z=6# #x+2y+3z=10# #x+2y+az=b#

#a != 3#, #b# can be any value

#[(1, 1, 1 | 6),(1, 2, 3 | 10), (1, 2, a | b)]#
Row #2 - 1# and #3 -1#
#=[(1, 1, 1 | 6),(0, 1, 2 | 4), (0, 1, (a-1) | (b-6))]#
Row #1 -2# and #3-2#
#=[(1, 0, -1 | 6),(0, 1, 2 | 4), (0, 0, (a-3) | (b-10))]#
To find unique solution #(b-10)/(a-3)# must be defined, so, #a != 3#

How can I find #a, b#?