For Enthalpy? the formula and what answer you all got? The sum(product)-The sum(reactant)

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1 Answer
Dec 4, 2017

#CH_3OH to 2H_2+CO#

Methanol,
puu.sh

decomposes into hydrogen (#H-H#) and carbon monoxide (#C-=O#) gases, here.

We're breaking three #C-H# bonds, one #C-O# bond, one #O-H# bond, and forming two #H-H# bonds, and one #C-=O# bond.

Forming bonds is exothermic, and breaking bonds is endothermic, so with using your data,

#DeltaH = SigmaDeltaH_b - SigmaDeltaH_f#

where b and f indicate bonds broken and bonds formed, respectively. Hence

#DeltaH = (3mol * (413kJ)/(mol) + 1mol * (358kJ)/(mol) + 1mol * (436kJ)/(mol)) - (1mol * (1072kJ)/(mol) + 2mol * (432kJ)/(mol)) approx 97kJ#

is the enthalpy of this reaction, which is energetically unfavorable.