How do functional groups affect organic molecules?

1 Answer
Sep 24, 2015

Functional groups determine the identity of organic molecules

Explanation:

Functional groups are very important in organic chemistry since they determine the identity of these molecules and therefore, depict the chemical and physical properties of them.

For example, hydroxy groups OHOH is specific for alcohols. the general structure for alcohols is R-OHROH.

In a similar way, COOHCOOH is the functional group for carboxylic acids of a general structure R-COOHRCOOH.

For esters, the functional group is COOR', where esters have the general structure R-COOR'.

And so on.

with different functional groups, alcohols, carboxylic acids, and esters have different chemical and physical properties and therefore, different identity.

Let us take a specific example; Propane CH_3CH_2CH_3. Propane is a gaseous molecule at room temperature. Adding a hydroxy group to its structure we get CH_3CH_2CH_2-OH which is the propanol. Propanol is liquid at room temperature ( change on physical property ). Propanol can react thanks to the presence of the oxygen atom in its backbone, however, propane has very limited reactivity ( change on chemical property ).

There are many other functional groups such as:
Sulfides: R-S-R'
Thiols: R-SH
Ethers: R-O-R'
Anhydrides: R-CO-O-CO-R'
Ketones: R-CO-R'
Aldehydes: R-CO-H
Amides: R-CO-N(R')_2 or R-CO-NH_2 or R-CO-NHR'
Amines: R-NH_2 or R-NHR' or R-N(R')_2
Nitriles: R-CN
Alkyl halides: R-X where X is an element from group 17.
Alkenes: R-CH=CH-R'
Alkynes: R-C-=C-R'
etc.