I know that 180° is pi radians (consider the length of a half circle arc; it spans an angle of 180° and its length is pir or half the entire circle perimeter. But radians is (arc length)/(radius), so for your half circle you have that also spans pir/r=pi radians).
Now you can say that: (180°)/(25°) must have the same result as pi/x where x is the corresponding measure of 25° in radians:
Finally: x=(25°)/(180°)pi=5/36pi