How do you predict the products in acid-base reactions?

1 Answer

You predict the products of acid-base reactions by pairing each cation with the anion of the other compound.

Explanation:

Acid-base neutralization is a special case of double displacement reaction.

We can use the same techniques to predict the products.

In acids, the cation is always "H"^+.

Let's use the neutralization of stomach acid ("HCl") by milk of magnesia ["Mg(OH)"_2] as an example.

"HCl + Mg(OH)"_2 → ?

(a.) Divide the acid into "H"^+ ions and negative ions.

"HCl" → "H"^+ + "Cl"^"-"

(b.) Divide the base into positive ions and "OH"^"-" ions.

"Mg(OH)"_2 → "Mg"^"2" + "OH"^"-"

(c.) For products, combine the "H"^+ and "OH"^"-" ions to make "H"_2"O".

Then combine the positive and negative ions to make a salt.

Remember to balance the positive and negative charges in the salt.

In this case, "Mg"^"2+" and "Cl"^"-" make "MgCl"_2.

("H"^+ + "Cl"^"-") + ("Mg"^"2+" + "OH"^"-") → ("Mg"^"2+" + "Cl"^"-") + ("H"^+ + "OH"^"-")

"HCl + Mg(OH)"_2 → "MgCl"_2 + "H"_2"O"

(d.) Balance the equation.

"2HCl" + "Mg(OH)"_2 → "MgCl"_2 + 2"H"_2"O"

EXAMPLE

Complete and balance an equation for the reaction between "HBr" and "Al(OH)"_3.

Solution

"HBr" + "Al(OH)"_3 → "?"

("H"^+ + "Br"^"-") + ("Al"^"3+" + "OH"^"-") → ("Al"^"3+" + "Br"^"-") + ("H"^+ + "OH"^"-")

"HBr + Al(OH)"_3 → "AlBr"_3 +"H"_2"O"

"3HBr + Al(OH)"_3 → "AlBr"_3 + "3H"_2"O"