What information do you get from a differential scanning calorimetry plot?

1 Answer
Mar 31, 2014

Differential scanning calorimetry (DSC) is often used to study polymers. You heat a sample and a reference at the same rate. When the sample undergoes a phase transition, a different amount heat will flow to it than to the reference to maintain both at the same temperature. You plot the difference in heat flow as a function of temperature.


The melting of a solid is endothermic. The extra heat flow to maintain the temperature shows up as a peak on the DSC plot.


The top of the peak is the polymer's melting temperature, #T_m#.


When the sample crystallizes, less heat is required to raise the sample temperature. This shows up as a dip in the DSC plot.


The temperature at the lowest point of the dip is the polymer's crystallization temperature, #T_c#.


After a certain temperature, a polymer may undergo a glass transition. Its heat capacity increases. The middle of the slope represents the glass transition temperature, #T_g#.


A whole plot often looks something like this: