How many lone pairs are present on carbon?

pcpc

How many lone pairs of electrons (if any) are present on the carbon with negative formal charge?

1 Answer
Oct 26, 2017

There is the ONE lone pair on the carbanion....

Explanation:

H3CCH2CH2CH2

There are 7 electron around the carbanion carbon.....3 electrons from the shared covalent bonds of CH and CC, and TWO electrons based on the carbon, and two inner core electrons (formally the 1s2 set).

Because the ipso carbon claims 7 electrons, 2 from the lone pair, 2 from the CH bonds, 1 from the CC bond, and 2 inner core, the formal charge of carbon here is 1....(the nucular charge of carbon is of course +6, i.e. Z=6, and 67=1)...

Note that this is not a mere formalism: butyl-lithium contains the species as a polar organometallic molecule, and is widely used in organic chemistry, and represents this formalism.