We have the balanced equation:
#2C_2H_2(g)+5O_2(g)->4CO_2(g)+2H_2O(g)#
At #STP#, the molar volume is #22.7 \ "L"#.
First, we must convert #52# grams of acetylene into moles. Acetylene has a molar mass of #26.04 \ "g/mol"#. So here, there exist approximately
#(52color(red)cancelcolor(black)"g")/(26.04color(red)cancelcolor(black)"g""/mol")~~2 \ "mol"#
Now, we see that the mole ratio between #C_2H_2# is #2:4#. So, #2# moles of acetylene will fully produce #4# moles of #CO_2#.
Since we also have #2# moles of acetylene, we produce #4# moles of #CO_2#. Remember at #STP#, the molar volume is #22.7 \ "L"#, and so the volume of carbon dioxide produce would be
#4color(red)cancelcolor(black)"mol"*(22.7 \ "L")/(1color(red)cancelcolor(black)"mol")=90.8 \ "L"#