What is the percentage of lithium in lithium carbonate #(Li_2CO_3)#?

1 Answer
Apr 20, 2016

Acquiring the percentage requires the usage of "unified" units, meaning units that are equivalent across the board, because a percentage is really a unitless fraction (all the involved units must cancel out).

So, we can use #"g/mol"#, given that all atoms have an atomic mass, to compute the following:

#\mathbf(%"Li" = "quantity Li"/("quantity Li"_2"CO"_3)xx100%)#

#= \mathbf("quantity Li"/("quantity Li" + "quantity C" + "quantity O")xx100%)#

where the "quantity" can be any chosen unified unit, as long as we use the same units for both lithium and lithium carbonate.

The atomic masses needed are

  • #"Li"#: we only know a range (#6.938~6.997#) with decent certainty, so let's choose #"6.94 g/mol";#
  • #"C"#: #"12.011 g/mol",#
  • #"O"#: #"15.999 g/mol".#

Therefore, the total mass of lithium carbonate (#"Li"_2"CO"_3#) is

#= 2*6.94 + 12.011 + 3*15.999#

#=# #color(green)("73.888 g/mol")#.

Now, we use the mass of lithium in the compound to determine the percentage of it in the compound.

Given that a subscript #\mathbf(2)# indicates that there are two #"Li"# atoms in #"Li"_2"CO"_3#, we simply have

#color(blue)(%"Li") = "quantity Li"/("quantity Li"_2"CO"_3)xx100%#

#= (2*6.94 cancel"g/mol" "Li")/(73.888 cancel"g/mol" "Li"_2"CO"_3)xx100%#

#= color(blue)(18.8%),#

rounded to three sig figs.