Why is it necessary for temperatures to be converted to Kelvin, rather than being represented in Celcius when completing gas law equations?

1 Answer
Nov 19, 2017

Well, because one of the earliest gas laws established that volume was proportional to temperature....

Explanation:

i.e. #VpropT#...or #V=kT#

Now this was an experimental gas law (proposed contemporaneously by Charles, Dalton, and Gay Lusaac) and it proposed that as temperature decreased, the volume expressed by a given quantity of gas would decrease proportionally. And while real gases did CONDENSE at a low enuff temperature, gas behaviour was idealized, and this led to the proposal of an #"absolute zero"#, at which an #"ideal gas"# would have ZERO volume, and all molecular motion would cease.

And the value of #"absolute zero"# has been interpolated to be #-273.15# #""^@C#.

Alternative temperature scales, which put the freezing point of water at #0# #""^@C# or #32*F#, below which temperature many gases would still exist, thus have a negative component to the scale, and would imply a NEGATIVE volume....and I am still trying to figure that one out....