Because #"Avocado's number"# of #"atomic mass units"# has a mass of #1*g# precisely...
Explanation:
As always, #N_"Avogadro's number"-=6.022xx10^23*mol^-1# is the link between the atomic realm, about which we theorize, to the macro realm, of grams, kilograms, and litres, what we measure out on a laboratory bench. And the masses of #N_A# atoms are listed where?