How do I calculate vapor pressure of water?

1 Answer
Dec 20, 2014

You could use Antoine's equation to calculate the vapor pressure of water. Antoine's equation is a vapor pressure equation that describes the relationship between vapor pressure and temperature for pure components. So,

#log_10p = A - B/(C + T)#, where

#p# - the vapor pressure;
#T# - temperature;
#A#, #B#, #C# - constants specific to each substance.

You'd get #p = 10^(A-B/(C + T))#.

This equation is usually used with two sets of paramaters, a low-pressure paramater that describes the vapor pressure curve up to the normal boiling point, and a second paramater that covers the range from boiling point to critical point.

So, for water, the two sets of paramaters are

SET 1. #A# = 8.07131, #B# = 1730.63, #C# = 233.426 for temeperatures between #1# and #100^@C#;
SET 2. #A# = 8.14019, #B# = 1810.94, #C# = 244.485 for temperatures betwen #99# and #374^@C#.

Notice that you can use both sets of paramaters for temeperatures between #99# and #100^@C#.

Here's a diagram of what an Antoine curve would look like

http://en.wikipedia.org/wiki/Vapor_pressure