What is the structure of #"Si"_3"N"_4#?

1 Answer
Sep 11, 2015

I would expect that the three silicon atoms are each in between a pair of nitrogen atoms. Silicon can make two double bonds, or one triple bond and one single bond.

Here is what this looks like:
https://upload.wikimedia.org/

There are two lone valence electrons on the lewis structure at each nitrogen, and no lone valence electrons on each silicon.

The #"N"-="Si"-"N"# equilibrium geometry is linear (similar to acetylene), the #"Si"-"N"="Si"# equilibrium geometry is bent (due to the lone pair on nitrogen creating three bonding groups), and the #"N"="Si"="N"# equilibrium geometry is linear (similar to carbon dioxide).