Is #"HCl"# a strong acid? What about #"HF"#?

2 Answers
Sep 18, 2015

Yes.

Explanation:

#HCl# is a strong acid in water as well as in it's natural gaseous form, which means in a solution every molecule is ionized, whereas HF is a mild acid so in a solution there's some of it ionized and some it as HF.

The equations
#HCl rarr H_((aq))^+ + Cl_((aq))^-#
#HF harr H_((aq))^+ + F_((aq))^-#

This is partly because #Cl^-# is a very stable ion - it has a complete octet for instance - , so when it breaks away from the molecule it can stay that way.

While the same could apply to #F^-# for the same reasons, fluorine is very electronegative and as such the bond fluorine makes with the proton has a tendency to be restored.

In water, the only other strong acids are #HBr#, #HI#, #HNO_3# and the first proton of #H_2SO_4#.

In aqueous solution, #HCl# is classified as a very strong acid, undergoing almost complete ionization. On the other hand #HF#, is classified as a weak acid.

Explanation:

For the reaction,

#HX rightleftharpoons H^+ + X^-#, where #X# = #Cl#, the equilibrium lies strongly to the right. For #X# = #F#, the equilibrium lies to the left. Hydrochloric acid, therefore, is by definition a strong acid.

As physical scientists, however, we should seek quantitative measures of acidity. The #pK_a# of HCl #~~ -7#; whereas #pK_a# of HF = #3.14#.