A copper salt contains 25.5% Cu, 12.9% S, 25.6% O, and 36.0% water...what is the empirical formula of the hydrate?

1 Answer
May 31, 2016

CuSO45H2O

Explanation:

We ASSUME that there are 100g of copper salt, and work out the molar quantities:

Cu: 25.5g63.55gmol1 = 0.401mol Cu.

S: 12.9g32.06gmol1 = 0.401mol S.

O: 25.6g15.999gmol1 = 1.60mol O

H2O: 36.0g18.01gmol1 = 2.00mol H2O

To get the empirical formula, we divide thru by the LOWEST molar quantity, i.e. 0.401mol, to give:

CuSO45H2O, copper sulfate pentahydrate

I have treated the water here as I would normally treat an element; I am certainly free to do so inasmuch as we could dry the salt and measure the actual water loss.

What is the colour of this salt?