#"Why do they say the stronger the acid, the stronger the conjugate base?"#

1 Answer
Nov 24, 2016

Presumably, they simply made a mistake. Are you sure they didn't say, #"the weaker the acid, the stronger the conjugate base"#?

Explanation:

As you know, #pK_a# and #pK_b# are logarithmic functions, and are defined by the relationships, #pK_a=-log_(10)K_a#, #pK_b=-log_(10)K_b#.

Given this definition, it follows the smaller, that is the more negative, the #pK_a# value, the STRONGER the acid is. It is a bit counter-intuitive, and we have all made mistakes in interpretation.