What is the Lewis Dot Structure for #Mg_2^+#?

1 Answer
Feb 4, 2017

If I were to take you literally, it would be a rather unstable cation...

#["Mg"cdots"Mg"]^(+)#
(the dots are an interaction line for a half-bond, not electrons)

Its MO diagram would have one less valence electron than that for #"Mg"_2# (presumed in the gas phase!). This is the MO diagram for the NEUTRAL #"Mg"_2# dimer:

Take one valence electron out of the antibonding #sigma_(3s)^"*"#, and we have a bond order that changed from #1/2(2 - 2) = 0# to #1/2(2 - 1) = 1/2#.

Thus, MO theory suggests that #"Mg"_2^(+)# is more stable than #"Mg"_2#.


If you mean #"Mg"^(2+)#, it has no valence electrons, so there is not much of a Lewis dot structure to draw... in fact, we have already "drawn" it by writing its chemical symbol and charge.