Question #fd4b1

1 Answer
Stefan V.
Mar 9, 2017

Here's what's going on here.

Explanation:

I think that you're referring to a problem Tyler solved in one of his YouTube videos. The problem starts at the 8:03 minute mark.

The idea here is that the average atomic mass of an element is calculated by taking the weighted average of the atomic masses of its stable isotopes.

Now, weighted average means that each isotope contributes to the average atomic mass in proportion to its abundance.

In this case, lithium is said to have two stable isotopes. Right from the start, you can say that the percent abundances of the two isotopes must add up to give 100%.

This is equivalent to saying that their decimal abundances, which are simply the percent abundances divided by 100, must add up to give 1.

Why is that the case?

Because lithium has only two stable isotopes, which implies that there are only two isotopes that contribute to its average atomic mass.

So if we take x to be the decimal abundance of 6Li, we can say that the decimal abundance of 7Li must be equal to 1−x, since

decimal abundance 6Li x +decimal abundance 7Li 1−x =1

Now, the average atomic mass for lithium will be equal to

avg. atomic mass Li=atomic mass.6Li×decimal abundance.6Li+atomic mass.7Li×decimal abundance.7Li

Since you know that lithium has an average atomic mass of 6.941, you can set up the equation like this

6.941=6.015⋅x+7.016⋅(1−x)

You would then go on to solve this equation to get

x=0.075

This is the decimal abundance of 6Li. The decimal abundance of 7Li will be

1−0.075=0.925

To convert these to percent abundances, multiply them by 100%

For 6Li: 0.075⋅100%=7.5%

For 7Li: 0.925⋅100%=92.5%

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