How do you convert from %"w/v"%w/v to molarity?

1 Answer
May 15, 2017

We define %"w/v"%w/v as:

%"w/v" = "solute mass in g"/"solution volume in mL" xx 100%%w/v=solute mass in gsolution volume in mL×100%

By unit conversion, we have that "g" xx "mol"/"g" -> "mol"g×molgmol, and that "mL" xx "1 L"/"1000 mL" -> "L"mL×1 L1000 mLL. Define:

  • m_(solute)msolute for the solute mass in "g"g
  • V_(soln)Vsoln for the solution volume in "mL"mL
  • M_(solute)Msolute for the molar mass of the solute in "g/mol"g/mol

Therefore:

"Molarity" = (m_(solute)/V_(soln) xx 100%) xx (1000 "mL/L")/(100% xx M_(solute))Molarity=(msoluteVsoln×100%)×1000mL/L100%×Msolute

Or, rewriting in terms of %"w/v"%w/v and implied unit cancellation, we have:

bb("Molarity" ("mol"/"L") = 1000/(M_(solute))(%"w/v")/(100%))Molarity(molL)=1000Msolute%w/v100%

As an example, if we have a 37%37% "w/v"w/v aqueous "HCl"HCl solution, then:

color(blue)("Molarity" ("mol"/"L")) = 1000/(36.4609) (37cancel(%) "w/v")/(100cancel(%))

= color(blue)("10.15 mol/L")