Firstly recall that;
#1000ml = 1L#
#(Na = 23, color(white)(x) O = 16, color(white)(x) S = 32)#
#Molarity = "Moles of solute"/"Volume of Solvent or Solution"#
#"Moles of solute" = "Mass of solute"/"Molar mass of solute"#
#"Volume of solvent" = 1000ml = 1L#
#"Solute" = Na_2SO_4#
#"Mass of solute" = 142g#
#"Molar mass of solute" = (23 xx 2) + 32 + (16 xx 4) gmol^-1#
#color (white) (XXXXXXXXXX) = 46 + 32 + 64 gmol^-1#
#color (white) (XXXXXXXXXX) = 142 gmol^-1#
#rArr "Moles of solute" = (142cancelg)/(142 cancelgmol^-1)#
#rArr "Moles of solute" = 1mol#
#rArr Molarity = "Moles of solute"/"Volume of Solvent or Solution"#
#rArr Molarity = (1 mol)/(1 L)#
#rArr Molarity = 1 mol L^-1#