Question #50273

1 Answer
Nov 26, 2017

Photo initiated free radical polymerization to form a methyl branched polyether.

Explanation:

#n CH(CH_3) = CH(CH_3)# + #gamma# => #I-CH(CH_3)C*H(CH_3)#

#I-CH(CH_3)C*H(CH_3)# + #O = C(CH_3)_2#
=> #I-CH(CH_3)CH(CH_3) - O - C*(CH_3)_2 #

=> #I-CH(CH_3)CH(CH_3) - O - C(CH_3)_2 - [- CH(CH_3)CH(CH_3) - O - C*(CH_3)_2 ]_n ... -> ("terminated")#

This, of course, assumes perfect alkene to ketone sequencing without mixture segments of the butene interfering.