What mass of #"sodium azide"#, #Na^(+)N_3^(-)#, is required to evolve #11.3*L# of dinitrogen gas at #10^5*Pa# pressure, and #0# #""^@C#?

1 Answer
Dec 16, 2017

We need to represent the decomposition reaction of sodium azide...and get a mass of approx. #22*g# with respect to the salt.

Explanation:

#2NaN_3(s) rarr 2Na(s) + 3N_2(g)uarr#

This is in fact a redox reaction....sodium ion is reduced, and azide ion is oxidized to dinitrogen....

And under standard conditions of #273.15*K#, and a pressure of #10^5*Pa#, #1*mol# of Ideal Gas occupies #22.7*L#....

And #"moles of dinitrogen"=(11.3*L)/(22.7*L*mol^-1)=0.498*mol#...and we need #2/3# this molar quantity with respect to #"sodium azide."#

And thus a mass.....of #2/3xx0.498*molxx65.01*g*mol^-1~=22*g#