Are d electrons considered valence electrons?

1 Answer

Generally, no. But the situation gets a bit complex for high values of #n#

Explanation:

#d-#orbitals begin at a principle quantum number of #n=3#, and d electrons are not always valence electrons.

However, at higher values of #n# (such as in the lanthanides/actinides), it is possible for them to become involved in bonding, because the difference in energy between #d-#orbitals and the rest of the nearby orbitals becomes quite small, allowing for easier access to those #d# electrons.