The below are oxidation reactions. Explain why?

   Metal + oxygen -> Metal Oxide

Magnesium + Oxygen -> Magnesium
Oxide
Zinc + Oxygen -> Zinc Oxide

1 Answer
Jan 15, 2018

They are oxidation reactions ONLY WITH RESPECT to the metal....

Explanation:

Why? Because while the metal is oxidized, in that its oxidation number increases from #0# to #+II#, the oxidation number of dioxygen reduces from #0# to #-II#.... The point is that for every electron loss, every oxidation, there is a corresponding electron gain, a reduction...and dioxygen gas is one of the most potents oxidants...

And we can do this formally for the zinc.... Zinc is OXIDIZED to #Zn^(2+)#, i.e. electron loss....

#Zn(s) rarr Zn^(2+) + 2e^(-)#....charge and mass are balanced as is absolutely required....and dioxygen is reduced.....

#1/2O_2+2e^(-) rarr O^(2-)#

And we add the former to the latter so that we can eliminate the electrons.....

#Zn(s) +1/2O_2+2e^(-)rarr underbrace(Zn^(2+)+O^(2-))_"i.e. ZnO" + 2e^(-)#

...to give finally....

#Zn(s) +1/2O_2(g) rarr ZnO(s)#

Capisce?